Garlic
The strong sulfur smell of garlic foliage can help hide kale from aphids and cabbage moths that locate their host by scent. Effect is real but modest, so plant a border of garlic along the row rather than relying on it alone.
Onion
Onion tops give off a pungent smell that often reduces the number of egg-laying cabbage moths and aphids finding young kale. Onions also stay shallow-rooted and short, so they take little light or water from the kale.
Nasturtium
Nasturtium often pulls cabbage aphids and cabbage white butterflies onto itself first. Treat it as a sacrificial plant: check it weekly and pull or wash off the colonies, or the trap simply becomes a nursery beside your kale.
Dill
Dill's flat flower clusters feed hoverflies, lacewings, and the tiny parasitic wasps that attack cabbage worms and aphids. Let a few plants flower near the kale row rather than cutting every stem for the kitchen.
Celery
Gardeners have long paired celery with cabbage-family crops, and both do want the same steady moisture and rich soil. No mechanism has been demonstrated, so treat it as a convenient bedfellow rather than pest protection.