Garlic
Garlic's strong smell can help hide kale from aphids and cabbage moths that locate host plants by scent. Plant a row along the bed edge rather than a few scattered cloves, since the effect depends on volume.
Onion
Onion foliage carries the same pungent smell as garlic and often reduces early aphid landings on nearby kale. Its narrow leaves take little room, so it fits between kale plants without shading them.
Nasturtium
Cabbage worms and aphids often settle on nasturtium in preference to kale. It only works if you check the nasturtiums weekly and pull or treat the infested growth, otherwise it becomes a nursery feeding the whole bed.
Dill
Let a few dill plants flower and the flat umbrella of tiny blooms feeds hoverflies, lacewings, and the small parasitic wasps that attack cabbage worms and aphids. Keep it at the bed edge so it does not shade young kale.
Celery
Gardeners have long paired celery with cabbage-family crops, and both are said to benefit. No mechanism has been demonstrated, but they share a taste for steady moisture and rich soil, so growing them side by side is easy to manage.